化学气相渗透法制备碳化硅陶瓷复合材料

综述了化学气相渗透法制备连续纤维增强碳化硅陶瓷复合材料的过程，以及碳化硅陶瓷复合材料的性能及应用。     

Effects of the Fabrication Processes of NC-Si:H Films on Their Mechanical Properties

Studies of nanoindentation were performed on nc-Si:H films to evaluate the effects of the fabrication processes on their mechani-cal properties. It is observed that with the decrease of the SiH4 contents, the grain size of the films increases gradually, and as does the crystalline volume fraction. The smaller the grains become, the more homogeneous the films, and the more even the hardness as well as the modulus will be. The hardness and the modulus will increase with the substrate’s temperature rising. The hardness and the modulus of the nc-Si:H films on the Si substrate prove to be higher than those on the glass substrate given the same technology parameters. How-ever, the films on the glass substrate appear to be more homogeneous.     

喷射沉积过程中显微组织的形成机制

通过对沉积还纵剖面的组织分析，发现沉积坯在进缘、上下表面及中心部位的显微组织明显不同。边缘及上下表面区试样的退火试验研究表明，细小的枝晶碎块在高温退火过程中发生凝共和粗化，并导致近球状晶粒组织的形成。试验确定其生长服从：D2-D02=6.37×1020e(-70036.1/T)·τ，晶界迁移激活能Qg=582KJ／mol。并依赖于两种机制：（1）在喷射沉积过程中无强烈变形枝晶的均匀化；（2）变形及断裂枝晶的生长和粗化。     

Parylene真空涂覆新工艺研究

简述了Parylene真空沉积的机理,并对采用Parylene真空涂覆的涂层样件进行了全面的性能摸底试验。     

离子镀Ti(N,C)耐磨镀层成分与性能研究

 用空心阴极离子镀技术,在常用的不锈钢(1Cr18Ni9Ti)基材上,镀制Ti(N,C)耐磨镀层。对镀层的成分进行了分析,讨论了镀层成分的耐磨性,显微硬度和附着力的影响。通过对Ti(N,C)镀层与TiN和TiC镀层性能的对比,肯定了Ti(N,C)复合化合物镀层具有更优越的耐磨性和附着力。     

多层喷射沉积制备大尺寸耐热铝合金管坯的研究

采用多层喷射沉积工艺制备出了尺寸为Ф630 mm×250 mm×800 mm且质量较好的FVS0812耐热铝合金管坯,通过挤压获得了性能优良的大直径管材,并对管坯和挤压后管材的力学性能和微观结构进行了检测和分析.分析结果表明,多层喷射沉积制坯过程中,熔滴在沉积面的冷却速度约3.2×104 K@s-1～106K@s-1,熔滴凝固后在沉积坯中形成微细晶粒结构(200 nm～500 nm)和弥散分布的纳米析出相Al12(Fe,V)3Si(20nm～60 nm),使得沉积坯挤压致密后具有优异的性能.     

Electrolytic Passivation of Nitinol Shape Memory Alloy in Different Electrolytes

The corrosion behavior of the nitinol alloy was studied in various corrosion media of different Cl–ion concentrations. The results demonstrate that the Cl–ion concentration has significant influences on the corrosion behavior of the nitinol alloy. In order to enhance the corrosion resistance, protective films were generated on the surface of the nitinol alloy by means of the electrochemical passivation method, for which five different electrolytic solutions were investigated. The surface analysis indicates full growth of all samples pas-sivated in the different electrolytic solutions with layers, however, showing different morphological features. Without any defects like micro-cracks and pores, the surface of the samples passivated in the molybdate solution turns out smoother and denser than those pas-sivated in other solutions. It is shown that the electro-chemical passivation will reduce Ni content but increase Ti content in the surface, reaching the Mole ratio of Ti:Ni=9.01:1 on the outermost surface. Potentiodynamic polarization test demonstrates that the samples electrochemically passivated in the molybdate solution present a significant increase in breakdown potential due to titanium enrichment on the outermost surface.     

AB型聚酰亚胺单体的合成及气相沉积聚合研究

合成了三种AB型聚酰亚胺单体:4-(4-氨基苯氧基)邻苯二甲酸(单体4),4-(3-氨基苯氧基)邻苯二甲酸(单体7)和对(间)乙基4-(3-氨基苯氧基)邻苯二甲酸酯(单体8或9)。利用热失重分析(TGA)对比研究了这三种AB型聚酰亚胺单体的热行为。结果表明,单体4、单体7和单体8(9)在升温的过程中能发生热聚合生成聚酰亚胺。将单体4用于气相沉积聚合设备,得到了均匀透明的聚酰亚胺薄膜。对分子结构的修饰使单体8(9)较之单体7有更好的挥发性。     

CVD过程中温度对SiC涂层沉积速率及组织结构的影响

以CH3SiCl3 H2体系在1000～1300℃沉积了SiC涂层,研究了温度对涂层沉积速率的影响,应用自发形核理论解释了不同沉积温度下CVDSiC涂层的组织结构。结果表明,随着沉积温度的提高,CVDSiC涂层的沉积速率相应增大;1000～1200℃沉积过程为化学动力学控制过程,1200～1300℃沉积过程为质量转移控制,1000℃和1100℃沉积的SiC涂层表面光滑、致密;1200℃和1300℃沉积的SiC涂层表面粗糙、多孔;随着沉积温度的提高,CVDSiC涂层的晶体结构趋于完整,当温度超过1150℃时,涂层中除β SiC外还出现了少量α SiC。     

空气中微细电火花沉积铜合金工艺方法

提出了一种在空气中将工具电极丝黄铜材料沉积到工件上的新工艺方法。实现该方法的基本条件为:(1)工具电极接脉冲电源正极;(2)在空气中放电;(3)窄脉宽配合宽脉间。通过大量实验对微细电火花沉积加工的工艺规律进行了系统深入的研究,得出各主要工艺参数对沉积工艺效果的影响规律。最终以黄铜电极丝为工具电极,在高速钢工件表面上沉积出直径为0.19 mm、高度为7.35 mm的微小圆柱体。利用SEM、能谱分析和X射线衍射及显微硬度测试等方法对沉积物进行分析,得出该沉积物的组织结构、化学成分和硬度等方面的基本性质,为进一步研究三维沉积加工奠定了基础。